Product ID:AGEAN BLUE, RFK-402-SB
MSDS Date:12/03/1987
FSC:8010
NIIN:00N021211
MSDS Number: BLRVZ

O BRIEN CORP

450 EAST GRAND AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 415-761-2300

Info Phone: 415-761-2300

Cage: 30806

O BRIEN CORPORATION

SOUTH SAN FRANCISCO, CA 94080-6207 US

Cage: 72556

0.01

Fraction By Weight: 35%

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 5 - 10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:(ACUTE) EYE: POSSIBLE IRRIT. INHAL:
MAY CAUSE HDCH & RESP IRRIT. SKIN: POSSIBLE IRRIT/SENSIT. (ING 1)
INGEST: LOW ORDER OF TOX. POSS DEPRESS OF CNS. INHAL: IRRIT, BUT
NOT A LIKELY ROUTE OF EXPOS DUE T O VERY LOW VOLATILITY. EYE:
SEVERE IRRIT & POSS DMG. SKIN: MODERATE TO SEVERE IRRIT. POSS
ALLERGIC (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SKIN RXN IN SUSCEPTIBLE INDIVIDUALS.
(ING 2) INGEST: LOW ORAL TOX. NO TOX EFTS DUE TO INGEST ARE
DESCRIBED IN LITERATURE. INHAL: IRRIT TO UPPER RESP TRACT. EYE:
IRRIT. (CHRONIC) (ING 1) IN V ITRO LAB STUDIES HAVE SHOWN THAT SOME
EPOXY RESINS HAVE MUTAGENIC CAPABILITIES. ALL EPOXY RESINS SHOULD
BE (SUPP DATA)
Medical Cond Aggravated by Exposure:(ING 1) MAY AGGRAVATE EXISTING SKIN
CONDITIONS, A DERMAL ALLERGEN.

First Aid:INGEST: DRINK 1 OR 2 GLASSES OF WATER AND INDUCE VOMITING BY
PLACING FINGER AT BACK OF THROAT. CONSULT MD OR POIS CTL CTR IMMED.
INHAL: REMOVE FROM AREA TO FRESH AIR. EYE: IMMEDIATELY BEGIN
FLUSHING E YES WITH COOL WATER, OCCASIONALLY LIFTING LIDS TO ENSURE
THORO RINSING. CONTINUE FOR AT LEAST 15 MIN. WHILE FLUSHING EYES,
SEND FOR MD. SKIN: WASH THOROUGHLY WITH SOAP AND WATER.

Flash Point:>200F,>93C
Lower Limits:40 G/M3
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, DRY SAND.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DUST CLOUD OF 40 GRAMS PER CUBIC METER
CAN BE IGNITED BY A SPARK OF 20 MILLIJOULES.

Spill Release Procedures:SWEEP UP CAREFULLY OR USE EXPLOSION-PROOF
VACUUM CLEANER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP ALL EQUIP CLEAN & PROPERLY
GROUNDED TO AVOID STATIC ELEC BUILD-UP. KEEP WORK AREAS FREE OF
DUST THRU ADEQ VENT. AVOID PRLNGD CONT W/SKIN.
Other Precautions:DO NOT INGEST. KEEP OUT OF THE REACH OF CHILDREN.

Respiratory Protection:USE A PROPERLY FITTED NIOSH/MSHA APPROVED
MECHANICAL RESPIRATOR OR MASK TO AVOID BREATHING DUST. CAREFULLY
FOLLOW MFR INSTRUCTIONS FOR USE.
Ventilation:PROVIDE SUFFICIENT VENT IN VOLUME & PATTERN TO KEEP AIR
CONTAMINATION BELOW APPLICABLE OSHA PEL/ACGIH'S TLV TWA LIMIT.
Protective Gloves:SYNTHETIC RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE OVERALLS RECOMMENDED. REMOVE AND
WASH CONTAMINATED CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: TREATED AS POTENTIAL MUTAGENS. (ING 2) LABORATORY
STUDIES SHOW THAT INHAL EXPOS TO HIGH LEVELS (250 MG/KG) OF
TITANIUM DIOXIDE CAUSES CANCEROUS TUMORS IN RATS. THIS RESPONSE DID
NOT O CCUR AT LOWER EXPOS LEVS & MAY BE DUE TO HIGH LEVS OF DUST
OVERWHELMED THE NORMAL LUNG CLEARANCE MECHANISMS.

HCC:N1
Vapor Pres:SEE INGRED
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
WATER.
Stability Condition to Avoid:STATIC ELECTRICAL CHARGES.
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CO, CO2 AND NO2.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.